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Beilstein J. Org. Chem. 2013, 9, 2088–2096, doi:10.3762/bjoc.9.245
Graphical Abstract
Figure 1: Structures of the investigated phosphorescent triscyclometalated iridium complexes.
Figure 2: Photodegradation of the different compounds in toluene under ambient atmosphere. Plotted is the rat...
Figure 3: Photodegradation behavior of the iridium complexes in CH2Cl2 and toluene solution and in a spin-coa...
Figure 4: Mass spectra of the identified halogenated degradation products of a) Ir(ppy)3 after 200 min of irr...
Figure 5: Degradation curves of Ir(piq)3 in benzene and benzene-d6 under ambient and inert conditions (left)....
Figure 6: DAD chromatogram showing the formation of two main degradation products (left) and their assigned m...
Figure 7: Degradation curves of Ir(ppy)3 in benzene and benzene-d6 under ambient and inert conditions, and ma...
Figure 8: (a) Degradation curves of Ir(Me-ppy)3 in benzene and benzene-d6 under ambient and inert conditions....
Figure 9: Degradation curves of Ir(F,CN-ppy)3 in benzene, benzene-d6 and toluene under ambient conditions and...